Developments Leading to Bohr's Model — JEE Main Chemistry MCQs with Solutions
Free JEE Main Chemistry Developments Leading to Bohr's Model MCQs with step-by-step solutions (30 questions). Part of Atomic Structure. Practise online on Prepizo — no login needed.
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Questions with solutions
Q1 — Developments Leading to Bohr's Model · easy · theory
The relationship between the speed (c), frequency (ν) and wavelength (λ) of electromagnetic radiation is:
A. c = λ/ν
B. c = νλ ✓ Correct
C. c = ν/λ
D. ν = cλ
Solution: For any electromagnetic wave, speed = frequency × wavelength, i.e. c = νλ.
Q2 — Developments Leading to Bohr's Model · easy · theory
The wavenumber (ν̄) of radiation is defined as:
A. The speed of light divided by frequency
B. The product of ν and λ
C. The reciprocal of wavelength (1/λ) ✓ Correct
D. The reciprocal of frequency
Solution: Wavenumber ν̄ = 1/λ, the number of waves per unit length (units m⁻¹ or cm⁻¹).
Q3 — Developments Leading to Bohr's Model · medium · numerical
The frequency of light of wavelength 600 nm (c = 3 × 10⁸ m/s) is:
A. $5 \times 10^{14}$ Hz ✓ Correct
B. $1.8 \times 10^{17}$ Hz
C. $5 \times 10^{12}$ Hz
D. $2 \times 10^{14}$ Hz
Solution: ν = c/λ = (3 × 10⁸)/(600 × 10⁻⁹) = 5 × 10¹⁴ Hz.
Q4 — Developments Leading to Bohr's Model · medium · numerical
The energy of a photon of frequency 5 × 10¹⁴ Hz (h = 6.626 × 10⁻³⁴ J s) is about:
A. $6.6 \times 10^{-19}$ J
B. $3.3 \times 10^{-19}$ J ✓ Correct
C. $3.3 \times 10^{-34}$ J
D. $1.3 \times 10^{-19}$ J
Solution: E = hν = (6.626 × 10⁻³⁴)(5 × 10¹⁴) ≈ 3.3 × 10⁻¹⁹ J.
Q5 — Developments Leading to Bohr's Model · medium · numerical
The energy of a photon of wavelength 400 nm (h = 6.626 × 10⁻³⁴ J s, c = 3 × 10⁸ m/s) is approximately:
A. $5.0 \times 10^{-19}$ J ✓ Correct
B. $5.0 \times 10^{-27}$ J
C. $8.0 \times 10^{-19}$ J
D. $2.5 \times 10^{-19}$ J
Solution: E = hc/λ = (6.626 × 10⁻³⁴ × 3 × 10⁸)/(400 × 10⁻⁹) ≈ 4.97 × 10⁻¹⁹ ≈ 5.0 × 10⁻¹⁹ J.
Q6 — Developments Leading to Bohr's Model · easy · theory
Which of the following electromagnetic radiations has the highest frequency?
A. Infrared
B. γ-rays ✓ Correct
C. X-rays
D. Ultraviolet
Solution: γ-rays have the shortest wavelength and therefore the highest frequency (and energy) among the given radiations.
Q7 — Developments Leading to Bohr's Model · easy · theory
Which of the following has the longest wavelength?
A. Visible light
B. Radio waves ✓ Correct
C. X-rays
D. Microwaves
Solution: Radio waves have the longest wavelength (and lowest frequency) in the electromagnetic spectrum.
Q8 — Developments Leading to Bohr's Model · medium · theory
The correct order of increasing wavelength for the following radiations is:
A. Infrared < UV < X-rays < γ-rays
B. γ-rays < X-rays < UV < Infrared ✓ Correct
C. UV < Infrared < X-rays < γ-rays
D. X-rays < γ-rays < UV < Infrared
Solution: Wavelength increases (frequency decreases) in the order γ-rays < X-rays < UV < visible < Infrared.
Q9 — Developments Leading to Bohr's Model · easy · theory
According to Planck's quantum theory, energy is emitted or absorbed only in discrete packets called:
A. Quanta (photons) ✓ Correct
B. Orbitals
C. Electrons
D. Nodes
Solution: Planck proposed that radiant energy is emitted/absorbed in whole-number multiples of a quantum, E = hν (a quantum of light is a photon).
Q10 — Developments Leading to Bohr's Model · easy · theory
In the equation E = hν, the constant h is the:
A. Planck constant (6.626 × 10⁻³⁴ J s) ✓ Correct
B. Speed of light
C. Avogadro number
D. Rydberg constant
Solution: h is Planck's constant, 6.626 × 10⁻³⁴ J s, relating a photon's energy to its frequency.
Q11 — Developments Leading to Bohr's Model · medium · theory
A perfect black body is one which:
A. Neither absorbs nor emits radiation
B. Absorbs and emits radiation of all frequencies ✓ Correct
C. Only reflects all radiation
D. Only transmits all radiation
Solution: An ideal black body is a perfect absorber and, when heated, a perfect emitter of radiation of all wavelengths.
Q12 — Developments Leading to Bohr's Model · medium · theory
The photoelectric effect is the:
A. Emission of light when electrons fall into a metal
B. Splitting of light into a spectrum
C. Ejection of electrons from a metal surface when light of suitable frequency strikes it ✓ Correct
D. Absorption of electrons by a gas
Solution: When light of frequency above a threshold hits a metal, electrons (photoelectrons) are ejected — the photoelectric effect.
Q13 — Developments Leading to Bohr's Model · medium · theory
In the photoelectric effect, the kinetic energy of the emitted electrons depends on the:
A. Frequency of the incident light ✓ Correct
B. Intensity of the incident light
C. Time of exposure
D. Area of the metal surface
Solution: The maximum kinetic energy of photoelectrons depends only on the frequency of the light (KEmax = hν − φ), not its intensity.
Q14 — Developments Leading to Bohr's Model · medium · theory
In the photoelectric effect, the number of photoelectrons ejected per second depends on the:
A. Intensity of the incident light ✓ Correct
B. Frequency of the incident light
C. Wavelength only
D. Work function only
Solution: The number of electrons ejected (hence the photocurrent) is proportional to the intensity of the light, provided ν > ν₀.
Q15 — Developments Leading to Bohr's Model · medium · theory
The minimum frequency of light required to eject an electron from a metal surface is called the:
A. Resonance frequency
B. Larmor frequency
C. Fundamental frequency
D. Threshold frequency ✓ Correct
Solution: The threshold frequency ν₀ is the minimum frequency below which no photoelectrons are emitted, whatever the intensity.
Q16 — Developments Leading to Bohr's Model · medium · theory
The work function (φ) of a metal is related to its threshold frequency (ν₀) by:
A. φ = hν₀²
B. φ = ν₀/h
C. φ = h/ν₀
D. φ = hν₀ ✓ Correct
Solution: The work function is the minimum energy to remove an electron: φ = hν₀.
Q17 — Developments Leading to Bohr's Model · medium · numerical
The work function of a metal is 3.3 × 10⁻¹⁹ J. Its threshold frequency (h = 6.6 × 10⁻³⁴ J s) is:
A. $5 \times 10^{14}$ Hz ✓ Correct
B. $2 \times 10^{14}$ Hz
C. $5 \times 10^{15}$ Hz
D. $1 \times 10^{15}$ Hz
Solution: ν₀ = φ/h = (3.3 × 10⁻¹⁹)/(6.6 × 10⁻³⁴) = 5 × 10¹⁴ Hz.
Q18 — Developments Leading to Bohr's Model · medium · numerical
Light of frequency 1 × 10¹⁵ Hz falls on a metal of work function 3.3 × 10⁻¹⁹ J (h = 6.6 × 10⁻³⁴ J s). The maximum kinetic energy of the ejected electrons is:
A. $3.3 \times 10^{-19}$ J ✓ Correct
B. $1.65 \times 10^{-19}$ J
C. $6.6 \times 10^{-19}$ J
D. $9.9 \times 10^{-19}$ J
Solution: KEmax = hν − φ = (6.6 × 10⁻³⁴ × 1 × 10¹⁵) − 3.3 × 10⁻¹⁹ = 6.6 × 10⁻¹⁹ − 3.3 × 10⁻¹⁹ = 3.3 × 10⁻¹⁹ J.
Q19 — Developments Leading to Bohr's Model · medium · theory
If the frequency of the incident light is less than the threshold frequency of the metal, then:
A. No electrons are ejected no matter how intense the light ✓ Correct
B. Electrons are ejected with high kinetic energy
C. Electrons are ejected only if the light is very intense
D. Electrons are ejected after a long time delay
Solution: Below the threshold frequency, no photoelectron is emitted regardless of intensity — a key point the wave theory could not explain.
Q20 — Developments Leading to Bohr's Model · medium · theory
The photoelectric effect was successfully explained by:
A. Einstein, using the particle (photon) nature of light ✓ Correct
B. Thomson, using the plum pudding model
C. Maxwell, using wave theory
D. Rutherford, using the nuclear model
Solution: Einstein (1905) explained the photoelectric effect by treating light as a stream of photons of energy hν.
Q21 — Developments Leading to Bohr's Model · medium · theory
The photoelectric effect provides direct evidence for the:
A. Nuclear model of the atom
B. Existence of neutrons
C. Particle nature of light ✓ Correct
D. Wave nature of light
Solution: The instantaneous, frequency-dependent ejection of electrons demonstrates that light behaves as particles (photons).
Q22 — Developments Leading to Bohr's Model · easy · theory
A spectrum consisting of bright coloured lines on a dark background is called a(n):
A. Band spectrum
B. Emission spectrum ✓ Correct
C. Absorption spectrum
D. Continuous spectrum
Solution: When excited atoms emit radiation, bright lines appear on a dark background — an emission (line) spectrum.
Q23 — Developments Leading to Bohr's Model · easy · theory
A spectrum showing dark lines superimposed on a bright continuous background is a(n):
A. Emission spectrum
B. Discharge spectrum
C. Absorption spectrum ✓ Correct
D. Line spectrum
Solution: When white light passes through a sample, atoms absorb specific wavelengths, leaving dark lines on the continuous spectrum — an absorption spectrum.
Q24 — Developments Leading to Bohr's Model · medium · theory
The spectrum of atomic hydrogen is a:
A. Band spectrum
B. Continuous spectrum
C. Broad rainbow
D. Line spectrum ✓ Correct
Solution: Atomic hydrogen emits radiation only at discrete wavelengths, producing a line spectrum — key evidence for quantised energy levels.
Q25 — Developments Leading to Bohr's Model · medium · theory
The line spectrum of an element is best described as its:
A. Random and unpredictable
B. Unique fingerprint (characteristic of that element) ✓ Correct
C. Continuous rainbow
D. Same as that of every other element
Solution: Each element produces a characteristic set of spectral lines, so line spectra can be used to identify elements.
Q26 — Developments Leading to Bohr's Model · medium · theory
The emission (line) spectrum of hydrogen is obtained when:
A. White light is passed through liquid hydrogen
B. An electric discharge is passed through hydrogen gas ✓ Correct
C. Hydrogen is compressed at high pressure
D. Hydrogen is cooled to a very low temperature
Solution: An electric discharge excites the hydrogen atoms; as electrons fall back to lower levels they emit light, giving the line spectrum.
Q27 — Developments Leading to Bohr's Model · medium · theory
The wavenumber of radiation of wavelength 500 nm is:
A. $5 \times 10^{6}$ m⁻¹
B. $2 \times 10^{-6}$ m⁻¹
C. $5 \times 10^{-7}$ m⁻¹
D. $2 \times 10^{6}$ m⁻¹ ✓ Correct
Solution: ν̄ = 1/λ = 1/(500 × 10⁻⁹ m) = 2 × 10⁶ m⁻¹.
Q28 — Developments Leading to Bohr's Model · medium · theory
Which of the following photons carries the most energy?
A. Yellow light
B. Red light
C. Blue light ✓ Correct
D. Green light
Solution: Among visible colours, blue light has the shortest wavelength (highest frequency), so E = hc/λ is largest for blue.
Q29 — Developments Leading to Bohr's Model · medium · theory
As the wavelength of a photon increases, its energy:
A. Decreases ✓ Correct
B. First increases then decreases
C. Increases
D. Remains constant
Solution: Since E = hc/λ, energy is inversely proportional to wavelength — larger λ means smaller energy.
Q30 — Developments Leading to Bohr's Model · medium · theory
For light above the threshold frequency, the photoelectric current is directly proportional to the:
A. Intensity of the incident radiation ✓ Correct
B. Work function of the metal
C. Frequency of the radiation
D. Wavelength of the radiation
Solution: Once ν > ν₀, increasing intensity increases the number of photons and hence the number of ejected electrons, so the photocurrent rises with intensity.